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Abstract. Tropical cirrus clouds play a critical role in the climate system and are a major source of uncertainty in our understanding of global warming. Tropical cirrus are affected by processes spanning a wide range of spatial and temporal scales, from ice microphysics on cloud scales to mesoscale convective organization and planetary wave dynamics. This complexity makes tropical cirrus clouds notoriously difficult to model and has left many important questions stubbornly unanswered. At the same time, their multi-scale nature makes them well positioned to benefit from the rise of global, high-resolution simulations of Earth's atmosphere and a growing abundance of remotely sensed and in situ observations. Rapid progress requires coordinated efforts to take advantage of these modern computational and observational abilities. In this Opinion, we review recent progress in cirrus studies, highlight important questions that remain unanswered, and discuss promising paths forward. We find that significant progress has been made in understanding the life cycle of convectively generated ``anvil cirrus and how their macrophysical properties respond to large-scale controls. On the other hand, much work remains to be done to understand how small-scale anvil processes and the climatological anvil radiative effect may respond to global warming. Thin, in situ-formed cirrus are now known to be closely tied to the thermal structure and humidity of the tropical tropopause layer (TTL), but uncertainty at the microphysical scale remains a significant barrier to understanding how these clouds regulate the TTL moisture and temperature budgets, as well as the mixing ratio of water vapor entering the stratosphere. Model representation of ice-nucleating particles, water vapor supersaturation, and ice depositional growth continue to pose great challenges to cirrus modeling. We believe that major advances in the understanding of tropical cirrus can be made through a combination of cross-tool synthesis and cross-scale studies conducted by cross-disciplinary research teams. 

The majority of Sun-like stars form with binary companions, and their dynamical impact profoundly shapes the formation and survival of their planetary systems. Demographic studies have shown that close binaries (a < 100 au) have suppressed planet-occurrence rates compared to single stars, yet a substantial minority of planets do form and survive at all binary separations. To identify the conditions that foster planet formation in binary systems, we have obtained high-angular-resolution, mm interferometry for a sample of disk-bearing binary systems with known orbital solutions. In this poster, we present the case study of a young binary system, FO Tau (a ~ 22 au). Our ALMA observations resolve dust continuum (1.3 mm) and gas (CO J=2-1) from each circumstellar disk allowing us to trace the dynamical interaction between the binary orbit and the planet-forming reservoir. With these data we determine individual disk orientations and masses, while placing these measurements in the context of a new binary orbital solution. Our findings suggest that the FO Tau system is relatively placid, with observations consistent with alignment between the disks and the binary orbital plane. We compare these findings to models of binary formation and evolution, and their predictions for disk retention and planet formation. 

The chemistry of zirconium-based metal-organic polyhedra (ZrMOPs) is often limited by their poor solubilities. Despite their attractive features—including high yielding and facile syntheses, predictable topologies, high stability, and tunability—problematic solubilities have caused ZrMOPs to be under-studied and under-applied. Although these cages have been synthesized with a wide variety of carboxylate-based bridging ligands, we explored a new method for ZrMOP functionalization via node-modification, which we hypothesized could influence solubility. Herein, we report ZrMOPs with benzyl-, vinylbenzyl-, and trifluoromethylbenzyl-pendant groups decorating cyclopentadienyl moieties. The series was characterized by 1 H/ 19 F NMR, high-resolution mass spectrometry, infrared spectroscopy, and single-crystal X-ray diffraction. The effects of node functionalities on ZrMOP solubility were quantified using inductively coupled plasma mass spectrometry. Substitution caused a decrease in water solubility, but for certain organic solvents, e.g. DMF, solubility could be enhanced by ∼20×, from 16 μM for the unfunctionalized cage to 310 μM for the vinylbenzyl- and trifluoromethylbenzyl-cages. 

Abstract TOI-1899 b is a rare exoplanet, a temperate warm Jupiter orbiting an M dwarf, first discovered by Cañas et al. (2020) from a TESS single-transit event. Using new radial velocities (RVs) from the precision RV spectrographs HPF and NEID, along with additional TESS photometry and ground-based transit follow-up, we are able to derive a much more precise orbital period of P = 29.090312 − 0.000035 + 0.000036 days, along with a radius of R p = 0.99 ± 0.03 R J . We have also improved the constraints on planet mass, M p = 0.67 ± 0.04 M J , and eccentricity, which is consistent with a circular orbit at 2 σ ( e = 0.044 − 0.027 + 0.029 ). TOI-1899 b occupies a unique region of parameter space as the coolest known ( T eq ≈ 380 K) Jovian-sized transiting planet around an M dwarf; we show that it has great potential to provide clues regarding the formation and migration mechanisms of these rare gas giants through transmission spectroscopy with JWST, as well as studies of tidal evolution. 

We present the discovery of TOI-1518b -- an ultra-hot Jupiter orbiting a bright star $V = 8.95$. The transiting planet is confirmed using high-resolution optical transmission spectra from EXPRES. It is inflated, with $$R_p = 1.875\pm0.053\,R_{\rm J}$$, and exhibits several interesting properties, including a misaligned orbit ($${240.34^{+0.93}_{-0.98}}$$ degrees) and nearly grazing transit ($$b =0.9036^{+0.0061}_{-0.0053}$$). The planet orbits a fast-rotating F0 host star ($$T_{\mathrm{eff}} \simeq 7300$$ K) in 1.9 days and experiences intense irradiation. Notably, the TESS data show a clear secondary eclipse with a depth of $$364\pm28$$ ppm and a significant phase curve signal, from which we obtain a relative day-night planetary flux difference of roughly 320 ppm and a 5.2$$\sigma$$ detection of ellipsoidal distortion on the host star. Prompted by recent detections of atomic and ionized species in ultra-hot Jupiter atmospheres, we conduct an atmospheric cross-correlation analysis. We detect neutral iron ($${5.2\sigma}$$), at $$K_p = 157^{+68}_{-44}$$ km s$$^{-1}$$ and $$V_{\rm sys} = -16^{+2}_{-4}$$ km s$$^{-1}$$, adding another object to the small sample of highly irradiated gas-giant planets with Fe detections in transmission. Detections so far favor particularly inflated gas giants with radii $$rsim 1.78\,R_{\rm J}$$; although this may be due to observational bias. With an equilibrium temperature of $$T_{\rm eq}=2492\pm38$$ K and a measured dayside brightness temperature of $$3237\pm59$$ K (assuming zero geometric albedo), TOI-1518b is a promising candidate for future emission spectroscopy to probe for a thermal inversion.